Hide
Show all
Kinetics of transesterifying multifeedstock oil into biodiesel
Abstract
The synthesis of biodiesel is typically performed using homogeneous catalysts and high-temperature transesterification methods. This research aims to investigate the kinetics of transesterification reactions in biodiesel synthesis using a blend of six different types of oils: coconut oil, palm oil, soybean oil, canola oil, sunflower oil, and waste cooking oil. An equal volume of each oil is used to combine the multifeedstock oil, totaling 300 ml. After pretreatment, the multifeedstock oil is heated to 30, 40, 50, and 60°C, combined with a methoxide solution, and blended for a variable number of time intervals of 10, 20, 30, 40, 50, and 60 minutes. After a 24-hour stay, the biodiesel is cleaned and separated from the centrifuge's water content. The biggest conversion, which was attained at 60°C with a reaction time of 60 minutes, was reported in the study's results. Utilizing a base catalyst in accordance with the second-order kinetics of the biodiesel transesterification reaction of multifeedstock oil.
Keywords
Full Text:
PDFReferences
H. N. Aulia, “Potency of Biodiesel Production from The
Local Used Frying Oil Through The Electrocatalysis
Method,†J. Ris. Teknol. Pencegah. Pencemaran Ind., vol.
, no. 1, pp. 40–52, 2023, doi:
21771/jrtppi.2023.v14.no1.p40-52.
L. M. Serrano-Bermúdez et al., “Kinetic models for
degumming and bleaching of phospholipids from crude palm
oil using citric acid and Super Flo B80® and Tonsil®,†Food
Bioprod. Process., vol. 129, pp. 75–83, 2021, doi:
1016/j.fbp.2021.07.005.
Z. Zhu et al., “Soybean biodiesel production using
synergistic CaO/Ag nano catalyst: Process optimization,
kinetic study, and economic evaluation,†Ind. Crops Prod.,
vol. 166, no. 666, p. 113479, 2021, doi:
1016/j.indcrop.2021.113479.
A. Bokhari, S. Yusup, S. Asif, L. F. Chuah, and L. Z. Y.
Michelle, Process intensification for the production of
canola-based methyl ester via ultrasonic batch reactor:
Optimization and kinetic study. INC, 2020.
M. Z. Salmasi, M. Kazemeini, and S. Sadjadi,
“Transesterification of sunflower oil to biodiesel fuel
utilizing a novel K2CO3/Talc catalyst: Process optimizations
and kinetics investigations,†Ind. Crops Prod., vol. 156, no.
July, 2020, doi: 10.1016/j.indcrop.2020.112846.
y = -1.9616x - 4.9704
R² = 0.962
-5.04
-5.035
-5.03
-5.025
-5.02
-5.015
-5.01
-5.005
-5
015 0.02 0.025 0.03 0.035
Constant (ln K)
Temperature, 1/T (C)
exp. data
Disseminating Information on the Research of Mechanical Engineering - Jurnal Polimesin Volume 22, No. 6, December 2024 624
V. B. Veljković et al., “Biodiesel production from corn oil:
A review,†Renew. Sustain. Energy Rev., vol. 91, no. April,
pp. 531–548, 2018, doi: 10.1016/j.rser.2018.04.024.
W. N. M. Wan Ghazali, R. Mamat, H. H. Masjuki, and G.
Najafi, “Effects of biodiesel from different feedstocks on
engine performance and emissions: A review,†Renew.
Sustain. Energy Rev., vol. 51, pp. 585–602, 2015, doi:
1016/j.rser.2015.06.031.
N. S. F. Stocks, Elements of Chemical Reaction Engineering.
D. Widayat, H. N. Aulia, D. Hadiyanto, and S. B. Sasongko,
“Kinetic study on ultrasound assisted biodiesel production
fromwaste cooking oil,†J. Eng. Technol. Sci., vol. 47, no. 4,
pp. 374–388, 2015, doi:
5614/j.eng.technol.sci.2015.47.4.3.
F. Trejo-Zárraga, F. de J. Hernández-Loyo, J. C. ChavarrÃaHernández, and R. Sotelo-Boyás, “Kinetics of
Transesterification Processes for Biodiesel Production,â€
Biofuels - State Dev., 2018, doi: 10.5772/intechopen.75927.
D. A. Iryani et al., “Production of biodiesel using
heterogeneous catalyst (K-Impregnated bleaching earth)
based on reactivated bleaching earth,†Road to Net-Zero
Energy Transit. Challenges Solut., vol. 2019, no. 101, pp. 1–
, 2022.
M. A. Kadi, N. Akkouche, S. Awad, K. Loubar, and M.
Tazerout, “Kinetic study of transesterification using particle
swarm optimization method,†Heliyon, vol. 5, no. 8, p.
e02146, 2019, doi: 10.1016/j.heliyon.2019.e02146.
A. Haryanto, A. C. Gita, T. W. Saputra, and M.
Telaumbanua, “First Order Kinetics of Biodiesel Synthesis
Using Used Frying Oil through Transesterification
Reaction,†Aceh Int. J. Sci. Technol., vol. 9, no. 1, pp. 1–11,
, doi: 10.13170/aijst.9.1.13297.
A. R. Y. Sunarti, A. Roesyadi, and F. Kurniawansyah,
“Transesterification of Kapok Seed Oil (Ceiba Pentandra)
into Biodiesel Using Natural Zeolite Catalysts,†J. Phys.
Conf. Ser., vol. 1845, no. 1, 2021, doi: 10.1088/1742-
/1845/1/012006.
H. N. Aulia, F. N. Hidayat, and T. Sriana, “Characteristic
study of biodiesel mixtures from used oil and diesel oil,†IOP
Conf. Ser. Mater. Sci. Eng., vol. 830, no. 2, 2020, doi:
1088/1757-899X/830/2/022014.
R. E. W. Jansson, Electrochemical reaction engineering, vol.
, no. 9. 1980.
DOI: http://dx.doi.org/10.30811/jpl.v22i6.5609
Refbacks
- There are currently no refbacks.
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
Ciptaan disebarluaskan di bawah Lisensi Creative Commons Atribusi-BerbagiSerupa 4.0 Internasional .
Alamat Surat :
Politeknik Negeri LhokseumaweJl. Banda Aceh-Medan Km 280
Buketrata, Lhokseumawe, 24301, Aceh, Indonesia